Disclaimer: Please contact Sophos Professional Services if you require assistance with your specific environment and special thanks to Sanket Shah for providing the Solution.
This Recommend Read shows you how to configure a DHCP server on an Alias IP
You may refer to the following KB for reference:
Add an alias
Go to Network> Interfaces, click Add interface and then select Alias.
Specify the following
Go to Network > DHCP > Server > Add.Create an Alias Network Range.Notes:
See the screenshot below.
To further verify. Go back to Network > DHCP > Servers.
Network > Interfaces
DHCP Leasing on a workstation
In command prompt
Type ipconfig /release and then Ipconfig /renew